erm, sorry croft
whilst your observation of air rising is correct, and I'm not sure if I have remembered it correctly, but the connection that you take off for the feed to the shower pump on the salamander, is connected to a dip tube that is about 150-200mm long
thus avoiding drawing off water that has air in it.
the air in the tank still has the ability to vent up the open vent
cavitation from a low pressure area caused by the pump drawing water from the bottom of the dip tube can still happen but it is much less likely as the cross sectional area at that point is comparatively large
unless I am mistaken!
russ